Artikel ; Online: Quasiperiodic behavior in the electrodeposition of Cu/Sn multilayers: extraction of activation energies and wavelet analysis.
Physical chemistry chemical physics : PCCP
2019 Band 21, Heft 37, Seite(n) 21057–21063
Abstract: Living systems are one of the many examples in which self-organizing systems yield more intricate structures than those that can be achieved using a "step-by-step" approach. This phenomenon can be observed in electrochemical organic synthesis, ... ...
Abstract | Living systems are one of the many examples in which self-organizing systems yield more intricate structures than those that can be achieved using a "step-by-step" approach. This phenomenon can be observed in electrochemical organic synthesis, oscillating metal deposition and in chemical clocks. There is a plenitude of temporal instabilities during self-organization, from ordinary period-one oscillations, going through quasiperiodicity, to the onset of chaos. Here, we describe the emergence of quasiperiodic behavior during the oscillatory electro-deposition of Cu/Sn. The time-series were characterized using a continuous wavelet transform in order to extract the oscillation frequency of the process with changes in temperature, and to calculate the apparent activation energies. Two different energy ranges are presented, and these are attributed to an activation barrier (∼50 kJ mol |
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Sprache | Englisch |
Erscheinungsdatum | 2019-09-17 |
Erscheinungsland | England |
Dokumenttyp | Journal Article |
ZDB-ID | 1476244-4 |
ISSN | 1463-9084 ; 1463-9076 |
ISSN (online) | 1463-9084 |
ISSN | 1463-9076 |
DOI | 10.1039/c9cp03605a |
Datenquelle | MEDical Literature Analysis and Retrieval System OnLINE |
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