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  1. Artikel: Adsorptive removal of chromium from aqueous solutions using flax (Linum usitatissimum): Kinetics and equilibrium studies

    Choudhury, Tasrina Rabia / Rahman, M. Safiur / Liba, Samia Islam / Islam, Aminul / Quraishi, Shamshad Begum / Begum, Bilkis Ara / Mustafa, Ahmad Ismail / Amin, Md. Nurul

    Environmental chemistry and ecotoxicology. 2022, v. 4

    2022  

    Abstract: Chromium (Cr) ions, discharging from different industrial activities, especially from leather tanning industries, are becoming a major threat for the environment and human health. Therefore, elimination of chromium ions from industrial effluents should ... ...

    Abstract Chromium (Cr) ions, discharging from different industrial activities, especially from leather tanning industries, are becoming a major threat for the environment and human health. Therefore, elimination of chromium ions from industrial effluents should be addressed with great attention. Hence, this study was conducted for evaluating the possibilities of using an agricultural waste “flax” to eliminate Cr (III) ions from aqueous solutions. In order to assess the effects of various experimental parameters (i.e., contact time, pH, adsorbent amount, initial chromium ion concentration and particle size) on Cr (III) ions adsorption process, the batch adsorption study was conducted. This study revealed that adsorption of Cr (III) ions by flax required 420 min to reach equilibrium. On the other hand, the maximum (~70%) Cr (III) ions removal was observed at pH value of 2.0. The desorption efficiency with 0.5 M KOH was found to be 90%. The Langmuir and Freundlich isotherms models were in better correlation with experimental data, according to equilibrium studies. Kinetic experiments showed that the first order kinetics with a rate constant of 0.01 min⁻¹. Use of real wastewater sample became a great success for removing of Cr (III). This result suggests that the flax plant has the potentiality to become an effective and environmentally friendly economical adsorbent for the removal of Cr (III) ions significantly from waste water.
    Schlagwörter Linum usitatissimum ; adsorbents ; adsorption ; agricultural wastes ; chromium ; desorption ; ecotoxicology ; flax ; human health ; leather ; pH ; particle size ; wastewater
    Sprache Englisch
    Umfang p. 132-139.
    Erscheinungsort Elsevier B.V.
    Dokumenttyp Artikel
    ISSN 2590-1826
    DOI 10.1016/j.enceco.2022.02.004
    Datenquelle NAL Katalog (AGRICOLA)

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  2. Artikel: Application of silver-assisted laser desorption ionization ultrahigh-resolution mass spectrometry for the speciation of sulfur compounds

    Acter, Thamina / Solihat, Nissa Nurfajrin / Kim, Sungjune / Uddin, Nizam / Mustafa, Ahmad Ismail / Shamsuddin, Sayed Md / Kim, Sunghwan

    Analytical and bioanalytical chemistry. 2020 Jan., v. 412, no. 1

    2020  

    Abstract: We herein report the optimization and application of silver cationization (Ag+) in combination with laser desorption ionization (LDI) ultrahigh-resolution mass spectrometry (UHR-MS) to determine the structures of the sulfur-containing compounds present ... ...

    Abstract We herein report the optimization and application of silver cationization (Ag+) in combination with laser desorption ionization (LDI) ultrahigh-resolution mass spectrometry (UHR-MS) to determine the structures of the sulfur-containing compounds present in heavy crude oil. A number of sulfur-containing model compounds were used to optimize the positive-ion mode LDI-MS conditions in the presence of a silver-complexing agent. Under the optimized LDI conditions, sulfur-rich heavy oil fractions were treated with the silver salt, where Ag+ coordinated with the sulfur atoms to speciate the sulfur species. The obtained results suggested that benzothiophenic, naphtheno-non-aromatic sulfides, and non-aromatic thiols were the major components present in the analyzed oil sample. Graphical abstract
    Schlagwörter cationization ; desorption ; mass spectrometry ; models ; oils ; petroleum ; silver ; sulfides ; sulfur ; thiols
    Sprache Englisch
    Erscheinungsverlauf 2020-01
    Umfang p. 243-255.
    Erscheinungsort Springer Berlin Heidelberg
    Dokumenttyp Artikel
    ISSN 1618-2642
    DOI 10.1007/s00216-019-02272-5
    Datenquelle NAL Katalog (AGRICOLA)

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  3. Artikel ; Online: Application of silver-assisted laser desorption ionization ultrahigh-resolution mass spectrometry for the speciation of sulfur compounds.

    Acter, Thamina / Solihat, Nissa Nurfajrin / Kim, Sungjune / Uddin, Nizam / Mustafa, Ahmad Ismail / Shamsuddin, Sayed Md / Kim, Sunghwan

    Analytical and bioanalytical chemistry

    2019  Band 412, Heft 1, Seite(n) 243–255

    Abstract: We herein report the optimization and application of silver cationization ( ... ...

    Abstract We herein report the optimization and application of silver cationization (Ag
    Sprache Englisch
    Erscheinungsdatum 2019-12-16
    Erscheinungsland Germany
    Dokumenttyp Journal Article
    ZDB-ID 201093-8
    ISSN 1618-2650 ; 0016-1152 ; 0372-7920
    ISSN (online) 1618-2650
    ISSN 0016-1152 ; 0372-7920
    DOI 10.1007/s00216-019-02272-5
    Datenquelle MEDical Literature Analysis and Retrieval System OnLINE

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