Artikel ; Online: Stereoselective Processes Based on σ-Hole Interactions
Molecules, Vol 27, Iss 14, p
2022 Band 4625
Abstract: The σ-hole interaction represents a noncovalent interaction between atoms with σ-hole(s) on their surface (such as halogens and chalcogens) and negative sites. Over the last decade, significant developments have emerged in applications where the σ-hole ... ...
Abstract | The σ-hole interaction represents a noncovalent interaction between atoms with σ-hole(s) on their surface (such as halogens and chalcogens) and negative sites. Over the last decade, significant developments have emerged in applications where the σ-hole interaction was demonstrated to play a key role in the control over chirality. The aim of this review is to give a comprehensive overview of the current advancements in the use of σ-hole interactions in stereoselective processes, such as formation of chiral supramolecular assemblies, separation of enantiomers, enantioselective complexation and asymmetric catalysis. |
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Schlagwörter | chalcogen bond ; enantioselectivity ; enantioseparation ; halogen bond ; σ-hole ; noncovalent interaction ; Organic chemistry ; QD241-441 |
Sprache | Englisch |
Erscheinungsdatum | 2022-07-01T00:00:00Z |
Verlag | MDPI AG |
Dokumenttyp | Artikel ; Online |
Datenquelle | BASE - Bielefeld Academic Search Engine (Lebenswissenschaftliche Auswahl) |
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